Asymmetric Reductive Dicarbofunctionalization of Alkenes via Nickel Catalysis
نویسندگان
چکیده
منابع مشابه
Diaminophosphine oxide ligand enabled asymmetric nickel-catalyzed hydrocarbamoylations of alkenes.
Chiral trivalent phosphorus species are the dominant class of ligands and the key controlling element in asymmetric homogeneous transition-metal catalysis. Here, novel chiral diaminophosphine oxide ligands are described. The arising catalyst system with nickel(0) and trimethylaluminum efficiently activates formamide C-H bonds under mild conditions providing pyrrolidones via intramolecular hydro...
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ژورنال
عنوان ژورنال: Synlett
سال: 2020
ISSN: 0936-5214,1437-2096
DOI: 10.1055/s-0040-1707900